3 edition of Gas-phase ion and neutral thermochemistry found in the catalog.
Gas-phase ion and neutral thermochemistry
by Published by the American Chemical Society and the American Institute of Physics for the National Bureau of Standards in New York
Written in English
|Other titles||Journal of physical and chemical reference data. v. 17 (Supplement no. 1)|
|Statement||Sharon G. Lias ... [et al.].|
|Contributions||Lias, Sharon G., 1935-, United States. National Bureau of Standards.|
|The Physical Object|
|Pagination||iii, 861 p. :|
|Number of Pages||861|
|LC Control Number||88070606|
Methyl, methyl-d3, and ethyl hydroperoxide anions (CH3OO-, CD3OO-, and CH3CH2OO-) have been prepared by deprotonation of their respective hydroperoxides in a stream of helium buffer gas. Photodetachment with nm ( eV) radiation was used to measure the adiabatic electron affinities: EA[CH3OO, X̃ 2A‘ ‘] = ± eV, EA[CD3OO, X̃ 2A‘ ‘] = ± . The gas phase ion chemistry of the acetyl cation and isomeric [C2H3O]+ ions. On the structure of the [C2H3O]+ daughter ions generated from the enol of acetone radical cation. Organic Mass Spectrometry , 18 (6),
Request PDF | Neutral and ion thermochemistry: Its present status and significance | This short account outlines the sources of thermochemical data that are important for gas phase ion . Experimental gas-phase ion/molecule clustering of COS+ with CO2 and N2O. International Journal of Mass Spectrometry and Ion Processes , 97 (2), DOI: /(90) Andreas J. Illies. Gas-phase ion-molecule reactions in dilute mixtures of dimethyl ether in krypton.
The appearance energy of a cation A + can be defined as the standard enthalpy of reaction (16), where a molecule AB in the gas phase at T= 0 K is ionized and excited to a state AB + * by means of an electron or a photon, followed by decomposition into the fragments A + and B, provided that A + and B are in their ground states and all the species, including the electron, . Gas phase ion chemistry is a field of science encompassed within both chemistry and is the science that studies ions and molecules in the gas phase, most often enabled by some form of mass far the most important applications for this science is in studying the thermodynamics and kinetics of reactions. For example, one application is in studying the .
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Buy Gas-Phase Ion and Neutral Thermochemistry (Journal of Physical and Chemical Reference Data) on FREE SHIPPING on qualified orders Gas-Phase Ion and Neutral Thermochemistry (Journal of Physical and Chemical Reference Data): Lias, Sharon G, Bartmess, John E, Liebman, Joel F, Holmes, John L, Levin, Rhoda D, Mallard, W Gary Cited by: Reference books (form) Additional Physical Format: Online version: Gas-phase ion and neutral thermochemistry.
New York: Published by the American Chemical Society and the American Institute of Physics for the National Bureau of Standards, © (OCoLC) Document Type: Book: All Authors / Contributors: Sharon G Lias; United States.
Gas Phase Ion and Neutral Thermochemistry by Sharon G. Lias,available at Book Depository with free delivery worldwide. Book Back; 0 Marked; Mark; Options Refworks Print Link Email Cite Request Get help Holdings.
Chemistry (A D Allen) Storage. QDG37 Browse Shelf. Gerstein Science. Reference 3 Below Gas-phase ion and neutral thermochemistry / Sharon G.
GAS-PHASE ION AND NEUTRAL THERMOCHEMISTRY, by S. Lias, John E. Bartmess, J. Liebman, J. Holmes, R. Levin, and W. Mallard (Supplement No. 1 to Volume 17)pp. ( MB) ATOMIC Gas-phase ion and neutral thermochemistry book IONIC SPECTRUM LINES BELOW ANGSTROMS; HYDROGEN THROUGH KRYPTON, by Raymond L.
Kelly (Supplement No. 1 to Volume 16). The carbon-hydrogen bond dissociation enthalpy (C-H BDE) of cubane ( ± 4 kJ/mol), together with properties relevant for its experimental determination using gas-phase ion thermochemistry.
A review of gas phase ion thermochemistry which is separated by the metal studied has been presented . Theoretical computational models are also being developed and verified by. Subsequent versions include “Gas-phase Ion and Neutral Thermochemistry” (or “GIANT Tables”), proton affinity evaluations, and now the NIST Webbook, which contains regularly updated and evaluated thermodynamic information on ions and neutrals.
In this review, recent progress in the study of the chemistry of actinide ions in the gas phase is summarized. The new results, obtained using various mass spectrometric techniques, encompass reactivity studies of bare and ligated actinide ions with inorganic and organic molecules, thermochemical studies of neutral and ionic actinide oxides, and solvation.
Abstract. The mass spectrometer can be regarded as a kind of chemistry laboratory, especially designed to study ions in the gas phase. [1,2] In addition to the task it is usually employed for — creation of mass spectra for a generally analytical purpose — it allows for the examination of fragmentation pathways of selected ions, for the study of ion-neutral reactions and more.
Neutral Thermochemical data compiled by Hussein Y. Afeefy, Gas-Phase Ion Thermochemistry: An in-depth explanation of gas phase ion data available from this site. NIST Organic Thermochemistry Archive: A description of. Lias's research works with 4, citations and 1, reads, including: Primary Modes of Decomposition of Superexcited n‐Alkane Molecules.
Using eV as urea ionization energy together with the measured onset energy for reaction, the CO(NH 2) 2 + → NH 3 + + HNCO loss dissociation energy in the ion is 97 kJ mol −1, i.e., more endothermic than in the neutral, whereas the isomerization barrier is smaller in the ion.
This explains why dissociative photoionization takes. Purchase Advances in Gas Phase Ion Chemistry, Volume 3 - 1st Edition.
Print Book & E-Book. ISBNThe gas phase ion-molecule chemistry of doubly charged fullerene cations (C(n)++ where n=46,48, 60 and 70) with neutral oxygen molecules, were investigated using a.
This has gradually evolved through various publications, notably ‘Gas-phase Ion and Neutral Thermochemistry’ (affectionately known as ‘the GIANT Tables’) and the most recent proton affinity evaluation, eventually leading to the very useful NIST WebBook, where updated and evaluated thermodynamic information on ions and neutrals of all.
The gas-phase thermochemistry of actinide monosulfides, AnS, was investigated experimentally and theoretically. Fourier transform ion cyclotron resonance mass spectrometry was employed to study the reactivity of An + and AnO + (An = Th, Pa, U, Np, Pu, Am and Cm) with CS 2 and COS, as well as the reactivity of the produced AnS + with oxidants (COS, CO 2.
Thermochemistry of simple transition metal species as determined by guided ion beam mass spectrometry is reviewed. Compounds which are discussed include metal hydrides (both ionic and neutral), metal methyls (ionic and neutral), ionic metal methylidenes and metal methylidynes, and bis-methyl metal ions.
Richardson D.E. () Applications of gas-phase electron-transfer equilibria in organometallic redox thermochemistry. In: Freiser B.S. (eds) Organometallic Ion Chemistry. Understanding Chemical Reactivity, vol Peptide Ion Fragmentation: The Structure of b-Type Ions.
The Need for Computational Chemistry: The Methylacetate Ion Story. A Problem with Neutral Thermochemistry: DfH(CH3CH2OOH) Revisited. Some Advice When Assigning Structures to Gas-Phase Ions. References to Part 1. PART II: IONS CONTAINING C AND POLYATOMIC.
M.T. Rodgers, P.B. Armentrout, in Comprehensive Coordination Chemistry II, Coordination to Doubly Charged Ions. Experimental gas-phase studies of the thermochemistry of complexes of multiply charged metal cations have largely focused on the alkaline earths with water as a ligand, M 2+ (H 2 O) x complexes, 1–5 although some transition metals (TMs) have .Gas Phase Ion Chemistry, Volume 2 covers the advances in gas phase ion chemistry.
The book discusses the stabilities of positive ions from equilibrium gas-phase basicity measurements; the experimental methods used to determine molecular electron affinities, specifically photoelectron spectroscopy, photodetachment spectroscopy, charge transfer, and collisional ionization; and the gas-phase.Go To: Top, Gas phase ion energetics data, References Data from NIST Standard Reference Database NIST Chemistry WebBook The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected on the basis of sound.